| Qualifying Session - Saturday |
| 1 | Felipe Massa |  | Ferrari | 1:21.375 | 1:20.597 | 1:21.421 |
| 2 | Fernando Alonso |  | McLaren | 1:21.609 | 1:20.797 | 1:21.451 |
| 3 | Kimi Raikkonen | | Ferrari | 1:21.802 | 1:20.741 | 1:21.723 |
| 4 | Lewis Hamilton | | McLaren | 1:21.120 | 1:20.713 | 1:21.785 |
| 5 | Robert Kubica |  | BMW Sauber | 1:21.941 | 1:21.381 | 1:22.253 |
| 6 | Jarno Trulli |  | Toyota | 1:22.501 | 1:21.554 | 1.22.324 |
| 7 | Nick Heidfeld | | BMW Sauber | 1:21.625 | 1:21.113 | 1:22.389 |
| 8 | Heikki Kovalainen |  | Renault | 1:21.790 | 1:21.623 | 1:22.568 |
| 9 | David Coulthard |  | Red Bull | 1:22.491 | 1:21.488 | 1:22.749 |
| 10 | Giancarlo Fisichella | | Renault | 1:22.064 | 1:21.677 | 1:22.881 |
| 11 | Nico Rosberg |  | Williams | 1:21.943 | 1:21.968 |
| 14 | Rubens Barrichello |  | Honda | 1:22.502 | 1:22.097 |
| 12 | Takuma Sato |  | Super Aguri | 1:22.090 | 1:22.115 |
| 13 | Jenson Button | | Honda | 1:22.503 | 1:22.120 |
| 15 | Anthony Davidson | | Super Aguri | 1:22.295 | no time |
| 16 | Vitantonio Liuzzi |  | Toro Rosso | 1:22.508 | no time |
| 17 | Ralf Schumacher | | Toyota | 1:22.666 |
| 18 | Alexander Wurz | | Williams | 1:22.769 |
| 19 | Mark Webber | | Red Bull | 1:23.398 |
| 20 | Adrian Sutil |  | Spyker | 1:23.811 |
| 21 | Christijan Albers | | Spyker | 1:23.990 |
| 22 | Scott Speed | | Toro Rosso | no time |
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| Barcelona, Spain |
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