| Qualifying Session - Saturday |
| 1 |  | Mark Webber |  | Red Bull | 1:23.619 | 1:21.773 | 1:20.981 |
| 2 |  | Sebastian Vettel | | Red Bull | 1:24.142 | 1:21.540 | 1:21.181 |
| 3 |  | Lewis Hamilton |  | McLaren | 1:24.370 | 1:22.148 | 1:21.961 |
| 4 |  | Fernando Alonso |  | Ferrari | 1:23.485 | 1:22.813 | 1:21.964 |
| 5 | | Jenson Button | | McLaren | 1:24.428 | 1:22.050 | 1:21.996 |
| 6 |  | Vitaly Petrov |  | Renault | 1:23.069 | 1:22.948 | 1:22.471 |
| 7 | | Nico Rosberg |  | Mercedes | 1:23.507 | 1:22.569 | 1:22.599 |
| 8 |  | Felipe Massa | | Ferrari | 1:23.506 | 1:23.026 | 1:22.888 |
| 9 |  | Pastor Maldonado |  | Williams | 1:23.406 | 1:22.854 | 1:22.952 |
| 10 | | Michael Schumacher | | Mercedes | 1:22.960 | 1:22.671 | no time |
| 11 |  | Sebastien Buemi |  | Toro Rosso | 1:23.962 | 1:23.231 |
| 12 |  | Sergio Perez |  | Sauber | 1:24.209 | 1:23.367 |
| 13 | | Jaime Alguersuari | | Toro Rosso | 1:24.049 | 1:23.694 |
| 14 |  | Kamui Kobayashi | | Sauber | 1:23.656 | 1:23.702 |
| 15 |  | Heikki Kovalainen |  | Lotus | 1:25.874 | 1:25.403 |
| 16 | | Paul di Resta |  | Force India | 1:24.332 | 1:26.126 |
| 17 | | Adrian Sutil | | Force India | 1:24.648 | 1:26.571 |
| 18 |  | Jarno Trulli | | Lotus | 1:26.521 |
| 19 | | Rubens Barrichello | | Williams | 1:26.910 |
| 20 | | Timo Glock |  | Virgin | 1:27.315 |
| 21 | | Vitantonio Liuzzi |  | Hispania | 1:27.809 |
| 22 |  | Narain Karthikeyan | | Hispania | 1:27.908 |
| 23 |  | Jerome d'Ambrosio | | Virgin | 1:28.556 |
| 24 | | Nick Heidfeld | | Renault | no time |
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| Barcelona, Spain |
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